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← ScienceWhich consequence results when approximating molecular orbitals via linear combination of atomic orbitals functions?
A)Electron density near nuclei increases
B)Variational principle energy is obeyed✓
C)Molecular wave functions become exact
D)Degeneracy of orbitals always increases
💡 Explanation
The variational principle energy is satisfied because the linear combination provides an upper bound to the true ground state energy. Therefore the approximate energy is greater than or equal to the true energy, rather than precisely matching it or having lower, invalid values.
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