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← ScienceWhich constraint reduces efficiency when a photovoltaic polymer's electron delocalization declines?
A)Charge carrier mobility decreases✓
B)Band gap widens significantly
C)Exciton dissociation increases greatly
D)Recombination rate shifts minimally
💡 Explanation
Reduced electron delocalization decreases the effectiveness of charge transport via the hopping mechanism, because the polymer's band structure becomes less conducive to movement; therefore, decreased mobility results, rather than changes in properties dominated by band gap physics.
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