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← ScienceWhich mechanism causes a solid catalyst's effectiveness to diminish over time in a chemical reactor?
A)Catalyst poisoning by reactant impurities✓
B)Thermal expansion inducing phase transition
C)Increased reactant concentration at saturation
D)Reduced reactor pressure inhibiting activity
💡 Explanation
When reactant stream impurities adsorb strongly to the catalyst surface, catalyst poisoning occurs because the active sites are blocked irreversibly, preventing reactant binding and reducing catalytic activity. Therefore catalyst poisoning results, rather than phase transition, saturation, or reduced pressure effects which depend on different physical properties.
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