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← ScienceWhich mechanism causes decreased thermal conductivity in liquid water above its density maximum at 4°C?
A)Increased phonon scattering from hydrogen bonds✓
B)Reduced molecular spacing decreasing collisions
C)Enhanced convective heat transport limitation
D)Lowered specific heat reducing energy transfer
💡 Explanation
Above 4°C, warming of water induces breaking and reformation of hydrogen bonds, leading to increased phonon scattering due to greater structural disorder and reduced long range order. Therefore decreased thermal conductivity results, rather than increased conductivity, as the dominant mechanism inhibiting phonon propagation changes above the density maximum.
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