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Which mechanism causes increased brittleness in polymers undergoing chain scission due to UV radiation?

A)Covalent bond breakage forming free radicals
B)Increased crystallinity aligns polymer chains
C)Hydrogen bond formation increases crosslinking
D)Van der Waals forces redistribute polymer chains

💡 Explanation

When polymers are exposed to UV radiation, chain scission occurs because UV photons break covalent bonds, generating free radicals that initiate further degradation, leading to shorter polymer chains and reduced molecular weight. Therefore brittleness increases, rather than increased crystallinity or crosslinking changes requiring different reaction conditions.

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