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← ScienceWhich mechanism dominates deformation when amorphous polymers approach glass transition?
A)Covalent breakage induces chain scission
B)Chain mobility increases via reptation✓
C)Crystallization forms stronger lamellae
D)Crosslinking density reinforces entanglement
💡 Explanation
As temperature raises, polymer chains gain kinetic energy; chain mobility increases substantially via reptation; because polymer backbones slide past each other more easily as thermal energy rises. Molecular reptation dominates, therefore, rather than chain scission or crystallization; these require significantly greater energy/organization.
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