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← ScienceWhich mechanism explains diatomic molecular oxygen's paramagnetic behavior?
A)Hund's rule of maximum multiplicity✓
B)Photoelectric effect threshold frequency
C)Pauli exclusion principle limitations
D)Debye screening length limitations
💡 Explanation
Unpaired electrons in the π* antibonding molecular orbitals cause paramagnetism because Hund's rule dictates electrons fill orbitals to maximize spin multiplicity. Therefore, O₂ is paramagnetic, rather than diamagnetic, due to these unpaired spins under Hund's rule.
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