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ā ScienceWhich mechanism limits conversion rate of ammonia synthesis over a heterogeneous iron catalyst at industrial conditions?
A)Nitrogen dissociation on the catalyst surfaceā
B)Hydrogen adsorption due to surface poisoning
C)Ammonia desorption at high partial pressures
D)Iron oxide formation above critical temperature
š” Explanation
The rate-determining step in ammonia synthesis is nitrogen dissociation because the triple bond in Nā requires significant activation energy and surface intermediates. Thus nitrogen dissociation rate limits conversion, rather than adsorption, desorption, or catalyst oxidation which occur due to different underlying causes.
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