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← ScienceWhich outcome diminishes catalyst effectiveness after prolonged use in three-way catalytic converters?
A)Active site surface area decreases✓
B)Increased support material surface area
C)Reactant concentration gradients equilibrate
D)Elevated exhaust gas total enthalpy
💡 Explanation
Reduced catalytic activity follows from catalyst poisoning. Decreased surface area through sintering lowers active surface sites, because the precious metals cluster and reduce effective platinum group exposure; therefore, conversion rates decline dramatically rather than increasing them via dispersion or enthalpy effects.
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