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← ScienceWhich outcome is observed when platinum spontaneously dewets from high-surface-area cerium oxide supports during CO oxidation catalysis?
A)Surface area increases exponentially
B)Reaction rate decays exponentially✓
C)Equilibrium shifts toward reactants
D)Activation energy threshold decreases
💡 Explanation
Reaction rate decays exponentially because during CO oxidation, metal sintering via Ostwald ripening reduces active platinum surface area; therefore, the reaction rate decreases rapidly rather than activation energy reduction alone dictating the observed catalytic activity.
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