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← ScienceWhich outcome results when a catalyst poisons the active sites during irreversible reaction?
A)Overall reaction rate immediately decreases✓
B)Equilibrium shifts toward product formation
C)Activation energy of reaction decreases
D)Reverse rate increases beyond forward rate
💡 Explanation
When a catalyst is poisoned, the active sites are blocked, hindering reactant adsorption and the subsequent reaction mechanism, so overall reaction rate decreases because effective catalyst concentration reduces. Therefore, the rate immediately drops rather than shifting equilibrium, activation energy changing, or reverse rate outweighing forward which would require a reversible reaction and changes in thermodynamic parameters.
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