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Which outcome results when electron shielding fails within heavy metal orbitals?

A)Outer electrons become more relativistic
B)Hybridization reduces for inner orbitals
C)Inner electrons become less shielded
D)Orbital energies become nearly degenerate

💡 Explanation

When electron shielding is ineffective, larger nuclear charge increases the velocity of inner electrons, increasing relativistic effects; **relativistic contraction** shrinks the *s* orbitals because of mass increase as velocity increases. Therefore, only s-orbitals are heavily affected, rather than uniform changes to energies.

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