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← ScienceWhich prevents spontaneous emission from excited atomic orbitals?
A)Selection rule forbidden transitions✓
B)Increased electron orbital hybridization
C)Enhanced vibrational energy levels
D)Quantum mechanical relativistic effects
💡 Explanation
Selection rules dictate possible transitions; spontaneous emission requires allowed transitions. The quantum mechanical prohibition of certain momentum changes due to selection rules removes the mechanism of spontaneous de-excitation, because only particular reductions in orbital spin or angular momentum are allowed rather than random shifts.
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