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← ScienceWhich risk increases significantly when designing polyethylene gas pipelines at low temperatures?
A)Increased brittleness and fracture initiation✓
B)Enhanced chemical resistance to hydrocarbons
C)Elevated long-term creep rate is observed
D)Reduced gas permeability through the polymer
💡 Explanation
Increased brittleness occurs because decreasing temperature reduces chain mobility and weakens the van der Waals forces between chains promoting brittle fracture rather than ductile yielding. Therefore, the initiation energy decreases because fracture becomes easier due to weakening intermolecular bonds.
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