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← ScienceWhich risk increases when applying excessive voltage during aluminum electroplating?
A)Anode passivation by aluminum oxide
B)Hydrogen gas evolution becomes substantial✓
C)Ionic conduction surpasses electronic
D)Electrostatic forces create surface defects
💡 Explanation
Excessive voltage accelerates electrolysis of water. This leads to hydrogen gas evolution via the Volmer–Heyrovsky mechanism, rather than aluminum deposition, because aluminum ion reduction is limited by transport; therefore hydrogen production increases, rather than oxide formation.
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