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Which risk increases when increasing burner temperature abruptly in a solid oxide electrolyzer cell (SOEC)?

A)Electrolyte oxygen ion vacancy formation
B)Steam concentration thermodynamic shift
C)Electrode interfacial polarization loss
D)Rapid electrode-electrolyte delamination

💡 Explanation

Rapid temperature excursions lead to differential thermal expansion, thus the failure risk is rapid electrode-electrolyte delamination. This occurs because of thermal shock, therefore the electrodes separate rather than maintain electrochemical equilibrium, because the protective ramp times minimise stress.

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