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Which risk increases when industrial ammonia synthesis catalysts experience thermal cycling?

A)Increased crystal lattice dislocation rate
B)Decreased reactant diffusion equilibrium
C)Enhanced product desorption efficiency rate
D)Reduced active site poisoning concentration

💡 Explanation

Thermal cycling causes increased crystal lattice dislocation rate because repeated heating and cooling induce stresses at grain boundaries. These stresses drive vacancy cluster aggregation, leading to microcrack formation; therefore accelerating dislocation formation, rather than promoting atomic rearrangement uniformly.

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