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Which risk increases when two aromatic molecules approach closely and their pi orbitals overlap?

A)Photoinduced electron transfer occurs
B)Vibrational frequency redshifts strongly
C)Quantum confinement decreases significantly
D)Hydrogen bonding becomes energetically prohibited

💡 Explanation

Photoinduced electron transfer efficiency rises because orbital overlap enhances electron tunneling between molecules, which promotes charge separation; therefore electron transfer dominates, rather than vibrational changes or hydrogen bonding disruptions which are less sensitive to orbital geometry.

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