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← ScienceWhich consequence results when Boltzmann's constant nears zero during molecular simulations?
A)Simulated diffusion rate decreases sharply✓
B)System temperature will exponentially increase
C)Equilibrium constant approaches the unity
D)Reaction order becomes highly unpredictable
💡 Explanation
Decreasing Boltzmann's constant effectively lowers the thermal energy. This means state transitions require increasingly specific energies, because detailed balance (Fluctuation-Dissipation Theorem) dictates thermally-activated events will become rarer, therefore diffusion decreases, rather than temperatures fluctuating wildly.
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