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Which effect occurs in a chemical reactor when space velocity exceeds catalyst turnover frequency?

A)Increased reactant concentration fluctuations
B)Decreased product selectivity towards desired outcome
C)Elevated activation energy from poisoning
D)Reduced heat transfer across catalyst bed

💡 Explanation

When space velocity exceeds catalyst turnover frequency, insufficient contact time hinders complete reaction, thus lower selectivity occurs because reaction rates are limited by surface interaction instead of bulk concentration. Therefore product selectivity decreases rather than altered reactant profiles because the catalyst performance is overwhelmed by process speed.

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