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Which mechanism rapidly decreases reaction rate when powdered catalyst surface area is significantly reduced?

A)Adsorption site blockage from fouling
B)Change in activation energy barrier
C)Immobilization of reactants via trapping
D)Reduction in catalyst particle collisions

💡 Explanation

When catalyst surface area is reduced, adsorption site blockage from fouling occurs because fewer active sites remain available for reactant molecules, hindering surface-mediated bond breaking or formation reactions. Therefore, reaction rate decreases, rather than altering EA, immobilizing reactants or collision frequency affecting the observed rate.

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