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← ScienceWhich outcome occurs when a catalyst particle size increases in a fixed-bed reactor during continuous reaction?
A)Increased internal diffusion limitations lower rate✓
B)Decreased bed pressure drop increases activity
C)Enhanced heat transfer prevents hot spots
D)Reduced external film resistance raises selectivity
💡 Explanation
When catalyst particle size increases, the diffusion path length within the porous catalyst increases, leading to higher internal diffusion limitations which restricts reactant access and slows the effective reaction rate. Therefore, lower rate caused by internal diffusion results, rather than altered pressure drop, heat transfer, or selectivity effects related to other mechanisms.
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