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← ScienceWhich outcome occurs when non-orthogonal atomic wave functions overlap?
A)Molecular orbital energy level splitting✓
B)Intersystem crossing becomes less likely
C)Singlet fission efficiency improves greatly
D)Resonance diminishes during energy transitions
💡 Explanation
Molecular orbital energy level splitting occurs because when non-orthogonal atomic orbitals combine, the resulting molecular orbital energies split based on constructive and destructive interference. Therefore, energy level splitting results, rather than intersystem crossing, because this deals with configuration interaction.
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