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← ScienceWhich outcome results when mismatched molecular orbital symmetries undergo [forbidden] cycloaddition?
A)The reaction rate abruptly decreases✓
B)Steric hindrance increases significantly
C)Competing pathways dominate product outcome
D)Quantum tunneling likelihood is enhanced
💡 Explanation
The reaction rate decreases precipitously because, *orbital symmetry conservation*, a quantum mechanical effect dictates that only reactions with matching symmetry of the interacting molecular orbitals are allowed. Therefore the activation energy rises sharply rather than forming products, because reaction via other, non-concerted pathways becomes favorable.
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