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← ScienceWithin a catalytic converter, which mechanism limits the rate of hydrocarbon oxidation at low operating temperatures?
A)Surface adsorption of reactants✓
B)Equilibrium constant approaching zero
C)Active site poisoning by sulfur
D)Bulk diffusion within the substrate
💡 Explanation
At low temperatures, hydrocarbon oxidation is limited by the slow surface adsorption rate because the reactants lack sufficient kinetic energy to overcome adsorption energy barriers. Therefore, surface adsorption limits the rate, rather than equilibrium, poisoning or diffusion, which are significant at higher operating temperatures.
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