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Which outcome arises when an aqueous solution containing dissolved iron(III) chloride, FeCl3, is electrolyzed at high current density?

A)Evolution of chlorine gas occurs.
B)Iron metal plates on the cathode.
C)Oxygen is produced at the anode.
D)Hydrogen gas bubbles vigorously form.

💡 Explanation

Chlorine gas evolves because the high current density favors kinetics over thermodynamics; therefore, the chloride ions oxidize via electrolysis, rather than water oxidizing to produce oxygen because of a lower overpotential for chloride oxidation under the given conditions.

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